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Name Of Product CAS NO. Specification MSDS
(IAA) 3-Indoleacetic Acid 87-51-4 98% TC

3-Indoleacetic Acid

Indole-3-acetic acid Basic information

 Product Name:3-Indoleacetic Acid

 CAS:87-51-4

 MF:C10H9NO2

 MW:175.18

 EINECS:201-748-2

 Mol File:87-51-4.mol

 

Indole-3-acetic acid Chemical Properties

 Melting point:165-169 C (lit.)

 Boiling point:306.47C (rough estimate)

 Density 1.1999 (rough estimate)

 refractive index 1.5460 (estimate)

 Flash point:171C

 storage temp. -20C

 pka4.75(at 25)

 form crystalline

 color off-white to tan

 Water Solubility Soluble in ethanol (50 mg/ml), methanol, DMSO, and chloroform (sparingly). Insoluble in water.

 Sensitive Light Sensitive

 Decomposition 167 ºC

 Merck 14,4964

 BRN 143358

 Stability:Stable. Incompatible with strong oxidizing agents. Light sensitive.

 CAS DataBase Reference87-51-4(CAS DataBase Reference)

 NIST Chemistry ReferenceIndole-3-acetic acid(87-51-4)

 EPA Substance Registry SystemIndole-3-acetic acid (87-51-4)

Safety Information

 Hazard Codes Xi

 Risk Statements 36/37/38

 Safety Statements 22-24/25

 WGK Germany 3

 RTECS NL3150000

 8-10-23

 Hazard Note Irritant

 TSCA Yes

 HS Code 29339990

 ToxicityLD50 intraperitoneal in mouse: 150mg/kg

Indole-3-acetic acid Usage And Synthesis

 Chemical Propertieswhite to tan crystals

 UsesPlant growth regulator.

 DefinitionChEBI: A monocarboxylic acid that is acetic acid in which one of the methyl hydrogens has been replaced by a 1H-indol-3-yl group.

 Biosynthesis3-Indolylacetic acid is biosynthesised in plants from tryptophan by two pathways, the indolylpyruvic acid pathway being quantitatively the more important. Experiments with tomato shoots have shown the existence of a tryptophan transaminase, which catalyses the formation of indolylpyruvic acid, and a tryptophan decarboxylase, which catalyses the formation of tryptamine. The decarboxylation of indolylpyruvic acid is catalysed by indolylpyruvate decarboxylase, while indolylacetaldehyde dehydrogenase catalyses the oxidation of indolylacetaldehyde to indolylacetic acid.

 Biological Functions3-Indolylacetic acid (indole-3-acetic acid, IAA) is one of the auxins, which together with the gibberellins and abscisic acid, cyto- kinins and ethylene are hormones regulating the growth and development of plants. IAA is a ubiquitous constituent of higher plants and the most important auxin. Some other, non-indolic compounds, including phenyl- acetic acid biosynthesised in plants from phenylalanine, have similar properties and synthetic auxins have also been prepared.
In the plant, IAA conjugates with many compounds, including glucose and other sugars, and with aspartic and glutamic acids. This is probably a way of storing the hormone for future use.
IAA initiates many growth effects in plants, including geotropism and phototropism, development of the ovary, division of cells, enlargement in callus tissue, root formation and apical dominance. When fed to plants, the hormone causes growth up to a maximum, which depends on the type of tissue being fed, and thereafter inhibits further growth, probably through the formation of ethylene, which is growth-inhibitory. Stern tissues tolerate the highest levels of IAA and root tissues the lowest. In the plant, the most active sites of IAA synthesis are the young, expanding leaves.

 Agricultural UsesIndoleacetic acid (IAA), synthesized in the plant shoot tips, is a naturally occurring auxin. It is a plant growth promoter.

 Purification MethodsRecrystallise heteroauxin from EtOH/water [James & Ware J Phys Chem 89 5450 1985]. [Beilstein 22 III/IV 65.] Alternatively recrystallise 30g of the acid with 10g of charcoal in 1L of hot water, filter and cool when 22g of colourless acid separate. Dry it and store it in a dark bottle away from direct sunlight [Johnson & Jacoby Org Synth Coll Vol V 654 1973]. The picrate has m 178-180o. [Beilstein 22 H 66, 22 I 508, 22 II 50, 22 III/IV 1088.] It is a plant growth substance.

Indole-3-acetic acid Preparation Products And Raw materials

 Raw materialsIndolePotassium AcetateGlycolic acid

 Preparation Products1-METHYL-3-INDOLEACETIC ACID3-(2-chloroethyl)-1H-indole

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