Emamectin benzoate

 甲氨基阿维菌素苯甲酸盐

Introduction: The product is a semi-fermented and semi-synthesized insecticide of Avermectin kind. The intermediate emamectin is synthesized under certain conditions using AVM as material, then reacted with benzoic acid, and thus we get Emamectin Benzoate.

Emamectin Benzoate is more effective than Emamectin against the insects Lepidoptera. Notably, it is the best insecticide against cotton bell worm (Helicoverpa armigera), cole miller (plutella xylostella Linnaeus), etc. Which have been tolerant with such insecticides as pyrethroids, organic phosphates.
So, emamectin benzoate is an ideal substitute for high poisonous and high residual agricultural chemicals, also a kind of outstanding biological pesticide, which prevents and controls tolerantly harmful insects. Many agricultural chemicals factory use it as ideal technical for formulating and single medicament exploiting.

Common name: Emamectin benzoate

Another name: Proclaim; Proclaim 5SG; Denim; Methylamino abamectin benzoate; 4''-deoxy-4''-epi-N-methylaminoavermectin b1 benzoate; MK 244; MK-244; etc.

Chemical Name: A mixture containing 90% of (10E,14E,16E,22Z)-(1R,4S,5'S,6S, 6'R,8R,12S,13S,20R,21R,24S)-6'-[(S)-sec-butyl]-21,24-dihydroxy-5',11,13,22-tetra methyl-2-oxo-3,7,19-trioxatetracyclo[15.6.1.14,8.020,24]pentacosa-10,14,16,22-tetraene-6-spiro-2'-(5',6'-dihydro-2'H-pyran)-12-yl 2,6-dideoxy-3-O-methyl-4-O-(2,4,6- trideoxy-3-O-methyl-4-methylamino-a-L-lyxo-hexopyranosyl)-a-L-arabino-hexopyra noside and 10% of (10E,14E,16E,22Z)-(1R,4S,5'S, 6S,6'R,8R,12S,13S,20R,21R,24S) -21,24-dihydroxy-6'-isopropyl-5',11,13,22-tetramethyl-2-oxo-3,7,19-trioxatetracyclo [15.6.1.14,8.020,24]pentacosa-10,14,16,22-tetraene-6-spiro-2'-(5',6'-dihydro-2'H-pyra n)-12-yl 2,6-dideoxy-3-O-methyl-4-O-(2,4,6-trideoxy-3-O-methyl-4-methylamino-a -L-lyxo-hexopyranosyl)-a-L-arabino-hexopyranoside

Structural formula:
                   

Empirical formula: Emamectin B1a benzoate: C₅₆H₈₁NO₁₅; Emamectin B1b benzoate: C₅₅H₇₉NO₁₅

 

Mol. Weight: Bla: 1008.26  Blb: 994.23

CAS No.: 155569-91-8

Specifications 

Leading Emamectin benzoate supplier

Emamectin benzoate 70% TC

Emamectin benzoate 90% TC

Emamectin benzoate 95% TC

Emamectin benzoate 30% WSG/WDG 

Emamectin benzoate 5% WSG/WDG 

Emamectin benzoate 50g/L EC

Packing

BULK PACKING                                                     

Powder: 25KG/Bag, 25KG/Drum, 50KG/Drum etc.                    

Liquid: 200L/Drum, 20L/Drum, 10L/Drum ect.

SMALL PACKING

Powder: 1kg/Alu bag, 500g/Alu bag, 200g/Alu bag, 100g/Alu bag, 50g/Alu bag, 15g/Alu bag etc. 

Liquid: 5L/Drum, 1L/Bottle, 500ml/Bottle, 250ml/Bottle, 100ml/Bottle, 50ml/Bottle etc.

Customerized Packing label

Emamectin benzoate FAO standard 

Professional registration

HAZARDS IDENTIFICATION

Hazard statement(s)

H301  Toxic if swallowed.

H315  Causes skin irritation.

H319  Causes serious eye irritation.

H335  May cause respiratory irritation.

H400  Very toxic to aquatic life.

H410  Very toxic to aquatic life with long lasting effects.

Precautionary statement(s)

P261  Avoid breathing dust/fume/gas/mist/vapours/spray.

P280  Wear protective gloves/protective clothing/eye protection/face protection.

P301/P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302/P352  IF ON SKIN: Wash with plenty of soap and water

P305/P351/P338  IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P273  Avoid release to the environment.

Supplemental Hazard Statements none

MAMMALIAN TOXICOLOGY

Acute toxicity: 1) Acute oral LD50 for rats is 781.5 mg/kg. 2) Acute percutaneous LD50 for rabbits is >439 mg/kg. 3) Acute inhalation toxicity LC50 (4 h) for rats is 0.582 mg/l. 4) Skin irritation: Non-irritating to skin (rabbits). 5) Eye irritation: Slightly irritating to eyes (rabbits). 6) Skin sensitization for guinea pig: Not a skin sensitiser.

NOEL (1 year) for dogs is 0.25 mg/kg b.w. Other Not likely to be carcinogenic to humans, no evidence of a genotoxic or mutagenic potential.

ADI (JMPR) 0.0005 mg/kg b.w. [2014]. 

Classification: WHO Classification: II (Moderately hazardous)

EC Risk Classification: T - Toxic: R25, R23; Xn - Harmful: R21, R41, R48/25

N - Dangerous for the environment: R50, R53

ECOTOXICOLOGY

Effect on birds: Acute oral LD50 for Mallard ducks is 76 mg/kg. Effect on fish: Acute LC50 (96 h) for Rainbow trout is 0.174 mg/l. Effects on aquatic invertebrates: Acute EC50 (48 h) for Daphnia magna is 0.08 mg/l. Effects on algae: Acute EC50 (72 h) for Pseudokirchneriella subcapitata is 0.0072 mg/l. Effects on bees: Contact acute (48 h) LD50 is 0.035 μg/bee. Effects on earthworms: Acute 14 day LC50 is >1000 mg/kg.

ENVIRONMENTAL FATE

Animals Emamectin benzoate is partially metabolised but rapidly cleared (DT50 following oral dosing 34-51 h), indicating that it has no potential for bioaccumulation. Plants Metabolism has been investigated in lettuce, cabbage and sweet corn. It is non-systemic, and rapidly degrades in sunlight to various complex residues in which undegraded parent is the only significant residue. The residues were very low. Soil/Environment Rapidly degraded.

Usage: Emamectin benzoate was developed by Merck and Company. Mainly used to prevent and control harmful insects in Lepidoptera, Coleoptera, Homoptera, Mite. Widely used to prevent and control bollworm, cutworm of sugar beet, cole moth, cabbage caterpillar, armyworm, Mite, Prodenia litura(Fabricius) and so on harmful insects in many kinds of vegetables, fruit trees, tea, tobacco and cotton.

Application: Biochemistry Acts by stimulating the release of g-aminobutyric acid, an inhibitory neurotransmitter, thus causing paralysis. Mode of action Non-systemic insecticide which penetrates leaf tissues by translaminar movement. Paralyses the lepidoptera, which stop feeding within hours of ingestion, and die 2-4 dat. Uses For control of Lepidoptera such as armyworm, bollworm, cutworm, cole moth, cabbage caterpillar, Mite, Prodenia litura (Fabricius) and so on harmful insects in many kinds of crops including vegetables, fruit, brassicas, cotton, tobacco and pine trees.

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